Calories (thermoc.)
A thermochemical calorie (cal_th) is defined as exactly 4.184 joules. It is roughly the energy needed to warm one gram of water by one degree Celsius.
Therm (US)
A US therm is 105,480,400 joules, which is 100,000 Btu (59°F) and roughly the energy in 100 cubic feet of natural gas. US gas bills are often given in therms.